Free radical oxidation reaction for selectively solvatochromic sensors with dynamic sensing ability

A novel BODIPY (boradiazaindacene) dye denoted as BODIPY-DT containing terpyridine unit has been designed and characterized. The dye is found to be selective and visual solvatochromic sensor toward DMF among test organic solvents. The sensing process displays time-controllable, dynamic signal outputs in the emission colors including red, purple, yellow and even white emission colors. It is presented that selective free radical oxidation reaction happens during the recognition process.     

Controllable soliton transition and interaction in nonlocal nonlinear media

Nonlinear Dynamics - Two kinds of controllable evolutions of optical solitons are predicted in nonlocal nonlinear media by gradually tuning the characteristic length of response function. On the...     

Electron tunneling through a coupled system of electron and phonon

We study the electron tunneling through a single level quantum dot in the presence of electron–phonon interaction. By using the Green’s function and canonical transformation methods, we calculated exactly the current. It is found that the current vs dot level exhibits satellite peaks even without occurring of phonon-assisted tunneling processes, and properties of the current are affected heavily by the strength of electron–phonon interaction and phonon temperature.     

Permutation trinomials over Fq3

We consider four classes of polynomials over the fields ${\mathbb{F}}_{q^3}$, $q=p^h$, $p>3$, $f_1(x)=x^{q^2+q-1}+A{x}^{q^2-q+1}+Bx$, $f_2(x)=x^{q^2+q-1}+A{x}^{q^3-q^2+q}+Bx$, $f_3(x)=x^{q^2+q-1}+A{x}^{q^2}-Bx$, $f_4(x)=x^{q^2+q-1}+A{x}^q-Bx$, where $A,B\in {\mathbb{F}}_q$. We find sufficient conditions on the pairs $(A,B)$ for which these polynomials permute ${\mathbb{F}}_{q^3}$ and we give lower bounds on the number of such pairs.     

Designing Solid Electrolyte Interfaces towards Homogeneous Na Deposition: Theoretical Guidelines for Electrolyte Additives and Superior High-Rate Cycling Stability

Metallic Na is a promising metal anode for large-scale energy storage. Nevertheless, unstable solid electrolyte interphase (SEI) and uncontrollable Na dendrite growth lead to disastrous short circuit and poor cycle life. Through phase field and ab initio molecular dynamics simulation, we first predict that the sodium bromide (NaBr) with the lowest Na ion diffusion energy barrier among sodium halogen compounds (NaX, X=F, Cl, Br, I) is the ideal SEI composition to induce the spherical Na deposition for suppressing dendrite growth. Then, 1,2-dibromobenzene (1,2-DBB) additive is introduced into the common fluoroethylene carbonate-based carbonate electrolyte (the corresponding SEI has high mechanical stability) to construct a desirable NaBr-rich stable SEI layer. When the Na||Na₃V₂(PO₄)₃ cell utilizes the electrolyte with 1,2-DBB additive, an extraordinary capacity retention of 94 % is achieved after 2000 cycles at a high rate of 10 C. This study provides a design philosophy for dendrite-free Na metal anode and can be expanded to other metal anodes.     

Surfactant-mediated wetting and spreading: Recent advances and applications

Surfactant-mediated wetting and spreading are ubiquitous. Understanding of these phenomena in-depth allows precise tailoring of wetting performance which can contribute to global challenges in the food supply chain, healthcare, ecology and industrial processes. The first part of this review shows how surfactants can be used to improve the efficacy of fertilisers and pesticides in agriculture, enhanced oil recovery, treatment of lung diseases and extinguishing fires involving flammable liquids. The second part provides analysis of recent studies on wetting and spreading over solid substrates. It includes discussion on the effect of surfactants on the outcome of the impact of liquid drops, the wetting state after impact, autophobic effect and spreading kinetics for both partial and complete wetting, including superspreading. Perspectives of future development in the area of surfactant-assisted wetting and spreading on solid substrates are outlined.     

几何画板模拟阿贝折射仪测折射率

几何画板模拟阿贝折射仪测量液体折射率的过程,相对传统教学手段,更加科学直观并动态演示。通过修改棱镜折射率和待测液体折射率的参数,通过直观几何光学分析,得到为何阿贝折射仪必须满足棱镜折射率大于待测折射率。利用程序易修改特点研究,棱镜不同顶角和考虑色散现象的模拟结果,定量研究差别。     

降雨冲刷对黄土公路边坡植物防护影响的试验研究

通过对裸露黄土公路边坡、厚层基材植草公路边坡、三维网植草公路边坡以及平台植树公路边坡的现场降雨冲刷试验,阐述了不同防护型式的公路黄土边坡在降雨条件下的坡面径流、含泥量以及坡面冲刷情况,得出了"降雨对边坡坡面的侵蚀过程,首先是从雨滴直接打击土体开始,进而引起溅蚀,分散土粒,紧接着发生超渗径流造成坡面冲刷。"以及"对坡面破坏最大的是坡顶上方来水"等重要结论。验证了坡面植物防护以及平台植树等防护方法可以有效降低降雨冲刷对坡面的侵蚀破坏,为黄土地区公路边坡植物防护的设计施工以提供了可靠的依据。     

A novel eudesmene sesquiterpenoid from <Emphasis Type="Italic">Schisandra sphenanthera</Emphasis> stems

Chemical investigation on the stems of Schisandra sphenanthera has afforded a novel eudesmene-type sesquiterpenoid, schisansphene A (1), and a known compound, alismol (2). Their structures and configurations were elucidated by spectroscopic methods, including 2D NMR techniques.